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Coordination chemistry of polynitriles. Part 9. Decacyanoferrocene revisited: crystal and molecular structure of cis-[{C(5)(CN)(5)}(2)(MeCN)(4)Fe]

The reaction of Ag[C(5)(CN)(5)] with anhydrous FeCl(2) in acetonitrile leads to colourless crystals of tetrakis(acetonitrile-κN)bis(pentacyanocyclopentadienido-κN)iron(II) acetonitrile 1.8-solvate, [Fe(C(10)N(5))(2)(CH(3)CN)(4)]·1.8CH(3)CN or cis-[{C(5)(CN)(5)}(2)(MeCN)(4)Fe]·1.8MeCN. The...

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Detalles Bibliográficos
Autores principales:	Sünkel, Karlheinz, Blockhaus, Tobias
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2022
Materias:	Research Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8815677/ https://www.ncbi.nlm.nih.gov/pubmed/35119387 http://dx.doi.org/10.1107/S2053229622000365

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