A free boratriptycene-type Lewis superacid

Bicyclic pyrazabole-bridged ferrocenes with BH groups at their bridgehead positions were prepared from [Li(thf)](2)[1,1′-fc(BH(3))(2)] and pyrazole or 3,5-dimethylpyrazole in the presence of Me(3)SiCl (1 or 1Me, respectively; 1,1′-fc = 1,1′-ferrocenylene); Me(3)SiH and H(2) are released as byproduct...

Descripción completa

Detalles Bibliográficos
Autores principales: Henkelmann, Marcel, Omlor, Andreas, Bolte, Michael, Schünemann, Volker, Lerner, Hans-Wolfram, Noga, Jozef, Hrobárik, Peter, Wagner, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8826627/
https://www.ncbi.nlm.nih.gov/pubmed/35282635
http://dx.doi.org/10.1039/d1sc06404e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8826627/
https://www.ncbi.nlm.nih.gov/pubmed/35282635
http://dx.doi.org/10.1039/d1sc06404e

Ejemplares similares