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A free boratriptycene-type Lewis superacid

Bicyclic pyrazabole-bridged ferrocenes with BH groups at their bridgehead positions were prepared from [Li(thf)](2)[1,1′-fc(BH(3))(2)] and pyrazole or 3,5-dimethylpyrazole in the presence of Me(3)SiCl (1 or 1Me, respectively; 1,1′-fc = 1,1′-ferrocenylene); Me(3)SiH and H(2) are released as byproduct...

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Detalles Bibliográficos
Autores principales:	Henkelmann, Marcel, Omlor, Andreas, Bolte, Michael, Schünemann, Volker, Lerner, Hans-Wolfram, Noga, Jozef, Hrobárik, Peter, Wagner, Matthias
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2021
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8826627/ https://www.ncbi.nlm.nih.gov/pubmed/35282635 http://dx.doi.org/10.1039/d1sc06404e

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