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Hydrogen bond activated glycosylation under mild conditions
Herein, we report a new glycosylation system for the highly efficient and stereoselective formation of glycosidic bonds using glycosyl N-phenyl trifluoroacetimidate (PTFAI) donors and a charged thiourea hydrogen-bond-donor catalyst. The glycosylation protocol features broad substrate scope, controll...
Autores principales: | Xiao, Ke, Hu, Yongxin, Wan, Yongyong, Li, XinXin, Nie, Qin, Yan, Hao, Wang, Liming, Liao, Jinxi, Liu, Deyong, Tu, Yuanhong, Sun, Jiansong, Codée, Jeroen D. C., Zhang, Qingju |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8826775/ https://www.ncbi.nlm.nih.gov/pubmed/35282639 http://dx.doi.org/10.1039/d1sc05772c |
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