Electronic structure studies reveal 4f/5d mixing and its effect on bonding characteristics in Ce-imido and -oxo complexes

This study presents the role of 5d orbitals in the bonding, and electronic and magnetic structure of Ce imido and oxo complexes synthesized with a tris(hydroxylaminato) [((2-(t)BuNO)C(6)H(4)CH(2))(3)N](3−) (TriNO(x)(3−)) ligand framework, including the reported synthesis and characterization of two...

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Detalles Bibliográficos
Autores principales: Moreau, Liane M., Lapsheva, Ekaterina, Amaro-Estrada, Jorge I., Gau, Michael R., Carroll, Patrick J., Manor, Brian C., Qiao, Yusen, Yang, Qiaomu, Lukens, Wayne W., Sokaras, Dimosthenis, Schelter, Eric J., Maron, Laurent, Booth, Corwin H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8827158/
https://www.ncbi.nlm.nih.gov/pubmed/35282640
http://dx.doi.org/10.1039/d1sc06623d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8827158/
https://www.ncbi.nlm.nih.gov/pubmed/35282640
http://dx.doi.org/10.1039/d1sc06623d

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