Bioinspired desaturation of alcohols enabled by photoredox proton-coupled electron transfer and cobalt dual catalysis

In the biosynthesis sterols an enzyme-catalyzed demethylation is achieved via a stepwise oxidative transformation of alcohols to olefins. The overall demethylation proceeds through two sequential monooxygenation reactions and a subsequent dehydroformylative saturation. To mimic the desaturation proc...

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Detalles Bibliográficos
Autores principales: Huang, Long, Ji, Tengfei, Zhu, Chen, Yue, Huifeng, Zhumabay, Nursaya, Rueping, Magnus
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8831637/
https://www.ncbi.nlm.nih.gov/pubmed/35145083
http://dx.doi.org/10.1038/s41467-022-28441-2

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8831637/
https://www.ncbi.nlm.nih.gov/pubmed/35145083
http://dx.doi.org/10.1038/s41467-022-28441-2

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