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Dioxygen Reactivity of Copper(I)/Manganese(II)-Porphyrin Assemblies: Mechanistic Studies and Cooperative Activation of O(2)

The oxidation of transition metals such as manganese and copper by dioxygen (O(2)) is of great interest to chemists and biochemists for fundamental and practical reasons. In this report, the O(2) reactivities of 1:1 and 1:2 mixtures of [(TPP)Mn(II)] (1; TPP: Tetraphenylporphyrin) and [(tmpa)Cu(I)(Me...

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Detalles Bibliográficos
Autores principales: Li, Runzi, Khan, Firoz Shah Tuglak, Hematian, Shabnam
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8839022/
https://www.ncbi.nlm.nih.gov/pubmed/35164265
http://dx.doi.org/10.3390/molecules27031000