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Dioxygen Reactivity of Copper(I)/Manganese(II)-Porphyrin Assemblies: Mechanistic Studies and Cooperative Activation of O(2)
The oxidation of transition metals such as manganese and copper by dioxygen (O(2)) is of great interest to chemists and biochemists for fundamental and practical reasons. In this report, the O(2) reactivities of 1:1 and 1:2 mixtures of [(TPP)Mn(II)] (1; TPP: Tetraphenylporphyrin) and [(tmpa)Cu(I)(Me...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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MDPI
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8839022/ https://www.ncbi.nlm.nih.gov/pubmed/35164265 http://dx.doi.org/10.3390/molecules27031000 |