Nucleophilic Substitution at Heteroatoms—Identity Substitution Reactions at Phosphorus and Sulfur Centers: Do They Proceed in a Concerted (S(N)2) or Stepwise (A–E) Way?

The mechanisms of three selected identity substitution reactions at phosphorus and sulfur occurring with stereospecific inversion have been investigated using density functional theory (DFT). The first identity reaction between methoxyl anion and methyl ethylphenylphosphinate 1 reported in 1963 has...

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Detalles Bibliográficos
Autores principales: Mikołajczyk, Marian, Cypryk, Marek, Gostyński, Bartłomiej, Kowalczewski, Jakub
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8839028/
https://www.ncbi.nlm.nih.gov/pubmed/35163860
http://dx.doi.org/10.3390/molecules27030599

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8839028/
https://www.ncbi.nlm.nih.gov/pubmed/35163860
http://dx.doi.org/10.3390/molecules27030599

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