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Methods for Predicting Ethylene/Cyclic Olefin Copolymerization Rates Promoted by Single-Site Metallocene: Kinetics Is the Key
In toluene at 50 °C, the vinyl addition polymerization of 4-vinyl-cyclohexene (VCH) comonomers with ethylene is investigated using symmetrical metallocene (rac-Et(Ind)(2)ZrCl(2)) combined with borate/TIBA. To demonstrate the polymerizations’ living character, cyclic VCH with linear-exocyclic(π) and...
Autores principales: | , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8839136/ https://www.ncbi.nlm.nih.gov/pubmed/35160449 http://dx.doi.org/10.3390/polym14030459 |