Enantioselective Cu(I)-catalyzed borylative cyclization of enone-tethered cyclohexadienones and mechanistic insights

The catalytic asymmetric borylation of conjugated carbonyls followed by stereoselective intramolecular cascade cyclizations with in situ generated chiral enolates are extremely rare. Herein, we report the enantioselective Cu(I)-catalyzed β-borylation/Michael addition on prochiral enone-tethered 2,5-...

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Detalles Bibliográficos
Autores principales: Jadhav, Sandip B., Dash, Soumya Ranjan, Maurya, Sundaram, Nanubolu, Jagadeesh Babu, Vanka, Kumar, Chegondi, Rambabu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8844005/
https://www.ncbi.nlm.nih.gov/pubmed/35165287
http://dx.doi.org/10.1038/s41467-022-28288-7

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8844005/
https://www.ncbi.nlm.nih.gov/pubmed/35165287
http://dx.doi.org/10.1038/s41467-022-28288-7

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