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Rhodium hydride enabled enantioselective intermolecular C–H silylation to access acyclic stereogenic Si–H

The tremendous success of stereogenic carbon compounds has never ceased to inspire researchers to explore the potentials of stereogenic silicon compounds. Intermolecular C–H silylation thus represents the most versatile and straightforward strategy to construct C–Si bonds, however, its enantioselect...

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Detalles Bibliográficos
Autores principales: An, Kun, Ma, Wenpeng, Liu, Li-Chuan, He, Tao, Guan, Guiyu, Zhang, Qing-Wei, He, Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8844420/
https://www.ncbi.nlm.nih.gov/pubmed/35165278
http://dx.doi.org/10.1038/s41467-022-28439-w