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Rh(2)(ii)-catalyzed enantioselective intramolecular Büchner reaction and aromatic substitution of donor–donor carbenes

The chiral dirhodium(ii) tetracarboxylate-catalyzed enantioselective intramolecular Büchner reaction of donor/donor-carbenes was reported and a series of valuable chiral polycyclic products were synthesized. Both aryloxy enynones and diazo compounds were efficient carbene precursors for this reactio...

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Detalles Bibliográficos
Autores principales: Zhu, Dong, Cao, Tongxiang, Chen, Kai, Zhu, Shifa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8848862/
https://www.ncbi.nlm.nih.gov/pubmed/35308865
http://dx.doi.org/10.1039/d1sc05374d