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Construction of vicinal 4°/3°-carbons via reductive Cope rearrangement
Herein reported is a strategy for constructing vicinal 4°/3° carbons via reductive Cope rearrangement. Substrates have been designed which exhibit Cope rearrangement kinetic barriers of ∼23 kcal mol(−1) with isoenergetic favorability (ΔG ∼ 0). These fluxional/shape-shifting molecules can be driven f...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8848919/ https://www.ncbi.nlm.nih.gov/pubmed/35308853 http://dx.doi.org/10.1039/d1sc06307c |