Combining metal–metal cooperativity, metal–ligand cooperativity and chemical non-innocence in diiron carbonyl complexes

Several metalloenzymes, including [FeFe]-hydrogenase, employ cofactors wherein multiple metal atoms work together with surrounding ligands that mediate heterolytic and concerted proton–electron transfer (CPET) bond activation steps. Herein, we report a new dinucleating PNNP expanded pincer ligand, w...

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Detalles Bibliográficos
Autores principales: van Beek, Cody B., van Leest, Nicolaas P., Lutz, Martin, de Vos, Sander D., Klein Gebbink, Robertus J. M., de Bruin, Bas, Broere, Daniël L. J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8849050/
https://www.ncbi.nlm.nih.gov/pubmed/35308864
http://dx.doi.org/10.1039/d1sc05473b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8849050/
https://www.ncbi.nlm.nih.gov/pubmed/35308864
http://dx.doi.org/10.1039/d1sc05473b

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