An organophotocatalytic late-stage N–CH(3) oxidation of trialkylamines to N-formamides with O(2) in continuous flow

We report an organophotocatalytic, N–CH(3)-selective oxidation of trialkylamines in continuous flow. Based on the 9,10-dicyanoanthracene (DCA) core, a new catalyst (DCAS) was designed with solubilizing groups for flow processing. This allowed O(2) to be harnessed as a sustainable oxidant for late-st...

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Detalles Bibliográficos
Autores principales: Mandigma, Mark John P., Žurauskas, Jonas, MacGregor, Callum I., Edwards, Lee J., Shahin, Ahmed, d'Heureuse, Ludwig, Yip, Philip, Birch, David J. S., Gruber, Thomas, Heilmann, Jörg, John, Matthew P., Barham, Joshua P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8849051/
https://www.ncbi.nlm.nih.gov/pubmed/35308839
http://dx.doi.org/10.1039/d1sc05840a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8849051/
https://www.ncbi.nlm.nih.gov/pubmed/35308839
http://dx.doi.org/10.1039/d1sc05840a

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