Photo-on-Demand Phosgenation Reactions with Chloroform for Selective Syntheses of N-Substituted Ureas and Isocyanates

[Image: see text] Two new reaction processes involving the in situ oxidative photochemical conversion of CHCl(3) to COCl(2) allowed selective syntheses of N-substituted ureas and isocyanates from amines. (I) A CHCl(3) solution containing an amine and an organic base under O(2) bubbling provided the...

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Detalles Bibliográficos
Autores principales: Muranaka, Ryo, Liu, Yue, Okada, Itsuumi, Okazoe, Takashi, Tsuda, Akihiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8851444/
https://www.ncbi.nlm.nih.gov/pubmed/35187373
http://dx.doi.org/10.1021/acsomega.1c07132

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8851444/
https://www.ncbi.nlm.nih.gov/pubmed/35187373
http://dx.doi.org/10.1021/acsomega.1c07132

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