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Photo-on-Demand Phosgenation Reactions with Chloroform for Selective Syntheses of N-Substituted Ureas and Isocyanates
[Image: see text] Two new reaction processes involving the in situ oxidative photochemical conversion of CHCl(3) to COCl(2) allowed selective syntheses of N-substituted ureas and isocyanates from amines. (I) A CHCl(3) solution containing an amine and an organic base under O(2) bubbling provided the...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8851444/ https://www.ncbi.nlm.nih.gov/pubmed/35187373 http://dx.doi.org/10.1021/acsomega.1c07132 |