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Combining Valence-to-Core X-ray Emission and Cu K-edge X-ray Absorption Spectroscopies to Experimentally Assess Oxidation State in Organometallic Cu(I)/(II)/(III) Complexes

[Image: see text] A series of organometallic copper complexes in formal oxidation states ranging from +1 to +3 have been characterized by a combination of Cu K-edge X-ray absorption (XAS) and Cu Kβ valence-to-core X-ray emission spectroscopies (VtC XES). Each formal oxidation state exhibits distinct...

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Detalles Bibliográficos
Autores principales: Geoghegan, Blaise L., Liu, Yang, Peredkov, Sergey, Dechert, Sebastian, Meyer, Franc, DeBeer, Serena, Cutsail, George E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8855422/
https://www.ncbi.nlm.nih.gov/pubmed/35050605
http://dx.doi.org/10.1021/jacs.1c09505