E-Selective Manganese-Catalyzed Semihydrogenation of Alkynes with H(2) Directly Employed or In Situ-Generated

[Image: see text] Selective semihydrogenation of alkynes with the Mn(I) alkyl catalyst fac-[Mn(dippe)(CO)(3)(CH(2)CH(2)CH(3))] (dippe = 1,2-bis(di-iso-propylphosphino)ethane) as a precatalyst is described. The required hydrogen gas is either directly employed or in situ-generated upon alcoholysis of...

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Detalles Bibliográficos
Autores principales: Farrar-Tobar, Ronald A., Weber, Stefan, Csendes, Zita, Ammaturo, Antonio, Fleissner, Sarah, Hoffmann, Helmuth, Veiros, Luis F., Kirchner, Karl
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8859827/
https://www.ncbi.nlm.nih.gov/pubmed/35211351
http://dx.doi.org/10.1021/acscatal.1c06022

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8859827/
https://www.ncbi.nlm.nih.gov/pubmed/35211351
http://dx.doi.org/10.1021/acscatal.1c06022

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