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E-Selective Manganese-Catalyzed Semihydrogenation of Alkynes with H(2) Directly Employed or In Situ-Generated
[Image: see text] Selective semihydrogenation of alkynes with the Mn(I) alkyl catalyst fac-[Mn(dippe)(CO)(3)(CH(2)CH(2)CH(3))] (dippe = 1,2-bis(di-iso-propylphosphino)ethane) as a precatalyst is described. The required hydrogen gas is either directly employed or in situ-generated upon alcoholysis of...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8859827/ https://www.ncbi.nlm.nih.gov/pubmed/35211351 http://dx.doi.org/10.1021/acscatal.1c06022 |