Dehydrogenative ester synthesis from enol ethers and water with a ruthenium complex catalyzing two reactions in synergy

We report the dehydrogenative synthesis of esters from enol ethers using water as the formal oxidant, catalyzed by a newly developed ruthenium acridine-based PNP(Ph)-type complex. Mechanistic experiments and density functional theory (DFT) studies suggest that an inner-sphere stepwise coupled reacti...

Descripción completa

Detalles Bibliográficos
Autores principales: Kar, Sayan, Luo, Jie, Rauch, Michael, Diskin-Posner, Yael, Ben-David, Yehoshoa, Milstein, David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8860191/
https://www.ncbi.nlm.nih.gov/pubmed/35308195
http://dx.doi.org/10.1039/d1gc04574a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8860191/
https://www.ncbi.nlm.nih.gov/pubmed/35308195
http://dx.doi.org/10.1039/d1gc04574a

Ejemplares similares