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Dehydrogenative ester synthesis from enol ethers and water with a ruthenium complex catalyzing two reactions in synergy

We report the dehydrogenative synthesis of esters from enol ethers using water as the formal oxidant, catalyzed by a newly developed ruthenium acridine-based PNP(Ph)-type complex. Mechanistic experiments and density functional theory (DFT) studies suggest that an inner-sphere stepwise coupled reacti...

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Detalles Bibliográficos
Autores principales:	Kar, Sayan, Luo, Jie, Rauch, Michael, Diskin-Posner, Yael, Ben-David, Yehoshoa, Milstein, David
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8860191/ https://www.ncbi.nlm.nih.gov/pubmed/35308195 http://dx.doi.org/10.1039/d1gc04574a

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