Cargando…

Enantioselective crossed intramolecular [2+2] photocycloaddition reactions mediated by a chiral chelating Lewis acid

In intramolecular [2+2] photocycloaddition reactions, the two tethered olefins can approach each other in a straight or in a crossed fashion. Despite the fact that the latter reaction mode leads to intriguing, otherwise inaccessible bridged skeletons, there has so far not been any enantioselective v...

Descripción completa

Detalles Bibliográficos
Autores principales: Rigotti, Thomas, Schwinger, Daniel P., Graßl, Raphaela, Jandl, Christian, Bach, Thorsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8864722/
https://www.ncbi.nlm.nih.gov/pubmed/35310494
http://dx.doi.org/10.1039/d2sc00113f