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Enantioselective crossed intramolecular [2+2] photocycloaddition reactions mediated by a chiral chelating Lewis acid

In intramolecular [2+2] photocycloaddition reactions, the two tethered olefins can approach each other in a straight or in a crossed fashion. Despite the fact that the latter reaction mode leads to intriguing, otherwise inaccessible bridged skeletons, there has so far not been any enantioselective v...

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Detalles Bibliográficos
Autores principales: Rigotti, Thomas, Schwinger, Daniel P., Graßl, Raphaela, Jandl, Christian, Bach, Thorsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8864722/
https://www.ncbi.nlm.nih.gov/pubmed/35310494
http://dx.doi.org/10.1039/d2sc00113f

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