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Phenanthrene: establishing lower and upper bounds to the binding energy of a very weakly bound anion

Quite a few molecules do not form stable anions that survive the time needed for their detection; their electron affinities (EA) are either very small or negative. How does one measure the EA if the anion cannot be observed? Or, at least, can one establish lower and upper bounds to their EA? We prop...

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Detalles Bibliográficos
Autores principales: Gruber, Elisabeth, Kollotzek, Siegfried, Bergmeister, Stefan, Zappa, Fabio, Ončák, Milan, Scheier, Paul, Echt, Olof
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8865840/
https://www.ncbi.nlm.nih.gov/pubmed/35156966
http://dx.doi.org/10.1039/d1cp04755h