Structural Changes in Monolayer Cobalt Oxides under Ambient Pressure CO and O(2) Studied by In Situ Grazing-Incidence X-ray Absorption Fine Structure Spectroscopy
[Image: see text] We have used grazing incidence X-ray absorption fine structure spectroscopy at the cobalt K-edge to characterize monolayer CoO films on Pt(111) under ambient pressure exposure to CO and O(2), with the aim of identifying the Co phases present and their transformations under oxidizin...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8883796/ https://www.ncbi.nlm.nih.gov/pubmed/35242268 http://dx.doi.org/10.1021/acs.jpcc.1c10284 |
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author | Gajdek, Dorotea Olsson, Pär A. T. Blomberg, Sara Gustafson, Johan Carlsson, Per-Anders Haase, Dörthe Lundgren, Edvin Merte, Lindsay R. |
author_facet | Gajdek, Dorotea Olsson, Pär A. T. Blomberg, Sara Gustafson, Johan Carlsson, Per-Anders Haase, Dörthe Lundgren, Edvin Merte, Lindsay R. |
author_sort | Gajdek, Dorotea |
collection | PubMed |
description | [Image: see text] We have used grazing incidence X-ray absorption fine structure spectroscopy at the cobalt K-edge to characterize monolayer CoO films on Pt(111) under ambient pressure exposure to CO and O(2), with the aim of identifying the Co phases present and their transformations under oxidizing and reducing conditions. X-ray absorption near edge structure (XANES) spectra show clear changes in the chemical state of Co, with the 2+ state predominant under CO exposure and the 3+ state predominant under O(2)-rich conditions. Extended X-ray absorption fine structure spectroscopy (EXAFS) analysis shows that the CoO bilayer characterized in ultrahigh vacuum is not formed under the conditions used in this study. Instead, the spectra acquired at low temperatures suggest formation of cobalt hydroxide and oxyhydroxide. At higher temperatures, the spectra indicate dewetting of the film and suggest formation of bulklike Co(3)O(4) under oxidizing conditions. The experiments demonstrate the power of hard X-ray spectroscopy to probe the structures of well-defined oxide monolayers on metal single crystals under realistic catalytic conditions. |
format | Online Article Text |
id | pubmed-8883796 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-88837962022-03-01 Structural Changes in Monolayer Cobalt Oxides under Ambient Pressure CO and O(2) Studied by In Situ Grazing-Incidence X-ray Absorption Fine Structure Spectroscopy Gajdek, Dorotea Olsson, Pär A. T. Blomberg, Sara Gustafson, Johan Carlsson, Per-Anders Haase, Dörthe Lundgren, Edvin Merte, Lindsay R. J Phys Chem C Nanomater Interfaces [Image: see text] We have used grazing incidence X-ray absorption fine structure spectroscopy at the cobalt K-edge to characterize monolayer CoO films on Pt(111) under ambient pressure exposure to CO and O(2), with the aim of identifying the Co phases present and their transformations under oxidizing and reducing conditions. X-ray absorption near edge structure (XANES) spectra show clear changes in the chemical state of Co, with the 2+ state predominant under CO exposure and the 3+ state predominant under O(2)-rich conditions. Extended X-ray absorption fine structure spectroscopy (EXAFS) analysis shows that the CoO bilayer characterized in ultrahigh vacuum is not formed under the conditions used in this study. Instead, the spectra acquired at low temperatures suggest formation of cobalt hydroxide and oxyhydroxide. At higher temperatures, the spectra indicate dewetting of the film and suggest formation of bulklike Co(3)O(4) under oxidizing conditions. The experiments demonstrate the power of hard X-ray spectroscopy to probe the structures of well-defined oxide monolayers on metal single crystals under realistic catalytic conditions. American Chemical Society 2022-02-16 2022-02-24 /pmc/articles/PMC8883796/ /pubmed/35242268 http://dx.doi.org/10.1021/acs.jpcc.1c10284 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Gajdek, Dorotea Olsson, Pär A. T. Blomberg, Sara Gustafson, Johan Carlsson, Per-Anders Haase, Dörthe Lundgren, Edvin Merte, Lindsay R. Structural Changes in Monolayer Cobalt Oxides under Ambient Pressure CO and O(2) Studied by In Situ Grazing-Incidence X-ray Absorption Fine Structure Spectroscopy |
title | Structural Changes in Monolayer Cobalt Oxides under
Ambient Pressure CO and O(2) Studied by In Situ Grazing-Incidence
X-ray Absorption Fine Structure Spectroscopy |
title_full | Structural Changes in Monolayer Cobalt Oxides under
Ambient Pressure CO and O(2) Studied by In Situ Grazing-Incidence
X-ray Absorption Fine Structure Spectroscopy |
title_fullStr | Structural Changes in Monolayer Cobalt Oxides under
Ambient Pressure CO and O(2) Studied by In Situ Grazing-Incidence
X-ray Absorption Fine Structure Spectroscopy |
title_full_unstemmed | Structural Changes in Monolayer Cobalt Oxides under
Ambient Pressure CO and O(2) Studied by In Situ Grazing-Incidence
X-ray Absorption Fine Structure Spectroscopy |
title_short | Structural Changes in Monolayer Cobalt Oxides under
Ambient Pressure CO and O(2) Studied by In Situ Grazing-Incidence
X-ray Absorption Fine Structure Spectroscopy |
title_sort | structural changes in monolayer cobalt oxides under
ambient pressure co and o(2) studied by in situ grazing-incidence
x-ray absorption fine structure spectroscopy |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8883796/ https://www.ncbi.nlm.nih.gov/pubmed/35242268 http://dx.doi.org/10.1021/acs.jpcc.1c10284 |
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