Complexities of Regioselective Ring-Opening vs Transcarbonylation-Driven Structural Metamorphosis during Organocatalytic Polymerizations of Five-Membered Cyclic Carbonate Glucose Monomers

[Image: see text] Rigorous investigations of the organobase-catalyzed ring-opening polymerizations (ROPs) of a series of five-membered cyclic carbonate monomers derived from glucose revealed that competing transcarbonylation reactions scrambled the regiochemistries of the polycarbonate backbones. Re...

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Detalles Bibliográficos
Autores principales: Shen, Yidan, Yang, Xin, Song, Yue, Tran, David K., Wang, Hai, Wilson, Jaye, Dong, Mei, Vazquez, Mariela, Sun, Guorong, Wooley, Karen L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8889557/
https://www.ncbi.nlm.nih.gov/pubmed/35253000
http://dx.doi.org/10.1021/jacsau.1c00545

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8889557/
https://www.ncbi.nlm.nih.gov/pubmed/35253000
http://dx.doi.org/10.1021/jacsau.1c00545

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