Palladium-catalyzed selective C–C bond cleavage and stereoselective alkenylation between cyclopropanol and 1,3-diyne: one-step synthesis of diverse conjugated enynes

The stereoselective synthesis of 1,3-enynes from 1,3-diynes is demonstrated by palladium-catalyzed selective C–C bond cleavage of cyclopropanol. Exclusive formation of mono-alkenylated adducts was achieved by eliminating the possibility of di-functionalization with high stereoselectivity. Indeed, th...

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Detalles Bibliográficos
Autores principales: Pati, Bedadyuti Vedvyas, Ghosh, Asit, Yadav, Komal, Banjare, Shyam Kumar, Pandey, Shalini, Lourderaj, Upakarasamy, Ravikumar, Ponneri C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8890101/
https://www.ncbi.nlm.nih.gov/pubmed/35340856
http://dx.doi.org/10.1039/d1sc04780a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8890101/
https://www.ncbi.nlm.nih.gov/pubmed/35340856
http://dx.doi.org/10.1039/d1sc04780a

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