Cargando…

A novel type of donor–acceptor cyclopropane with fluorine as the donor: (3 + 2)-cycloadditions with carbonyls

gem-Difluorocyclopropane diester is disclosed as a new type of donor–acceptor cyclopropane, which smoothly participates in (3 + 2)-cycloadditions with various aldehydes and ketones. This work represents the first application of gem-difluorine substituents as an unconventional donor group for activat...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Haidong, Tian, Lifang, Wang, Hui, Li, Zhi-Qiang, Zhang, Chi, Xue, Fei, Feng, Chao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8890111/
https://www.ncbi.nlm.nih.gov/pubmed/35340862
http://dx.doi.org/10.1039/d2sc00302c