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Dimerizing cascades of enallenamides reveal the visible-light-promoted activation of cumulated C–C double bonds

The visible-light-promoted activation of conjugated C–C double bonds is well developed, while that of cumulated systems is underexplored. We present the feasibility of this challenging approach. The localization of a triplet on an allenamide arm can be favored over that on a conjugated alkene. Allen...

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Detalles Bibliográficos
Autores principales: Serafino, Andrea, Chiminelli, Maurizio, Balestri, Davide, Marchiò, Luciano, Bigi, Franca, Maggi, Rai-mondo, Malacria, Max, Maestri, Giovanni
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8890112/
https://www.ncbi.nlm.nih.gov/pubmed/35340858
http://dx.doi.org/10.1039/d1sc06719b