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Developing organoboranes as phase transfer catalysts for nucleophilic fluorination using CsF

Despite the general high fluorophilicity of boron, organoboranes such as BEt(3) and 3,5-(CF(3))(2)C(6)H(3)–BPin are shown herein for the first time, to our knowledge, to be effective (solid to solution) phase-transfer catalysts for the fluorination of certain organohalides with CsF. Significant (up...

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Detalles Bibliográficos
Autores principales: Kirschner, Sven, Peters, Matthew, Yuan, Kang, Uzelac, Marina, Ingleson, Michael J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8890113/
https://www.ncbi.nlm.nih.gov/pubmed/35340859
http://dx.doi.org/10.1039/d2sc00303a