Enantioselective Copper-Catalyzed Synthesis of Trifluoromethyl-Cyclopropylboronates

[Image: see text] A copper-catalyzed enantioselective cyclopropanation involving trifluorodiazoethane in the presence of alkenyl boronates has been developed. This transformation enables the preparation of 2-substituted-3-(trifluoromethyl)cyclopropylboronates with high levels of stereocontrol. The p...

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Detalles Bibliográficos
Autores principales: Altarejos, Julia, Sucunza, David, Vaquero, Juan J., Carreras, Javier
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8895459/
https://www.ncbi.nlm.nih.gov/pubmed/34320310
http://dx.doi.org/10.1021/acs.orglett.1c02420

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8895459/
https://www.ncbi.nlm.nih.gov/pubmed/34320310
http://dx.doi.org/10.1021/acs.orglett.1c02420

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