Dissimilarity in the Chemical Behavior of Osmaoxazolium Salts and Osmaoxazoles: Two Different Aromatic Metalladiheterocycles

[Image: see text] The preparation of aromatic hydride-osmaoxazolium and hydride-oxazole compounds is reported and their reactivity toward phenylacetylene investigated. Complex [OsH(OH)(≡CPh)(IPr)(P(i)Pr(3))]OTf (1; IPr = 1,3-bis(2,6-diisopropylphenyl)imidazolylidene, OTf = CF(3)SO(3)) reacts with ac...

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Detalles Bibliográficos
Autores principales: Buil, María L., Esteruelas, Miguel A., Oñate, Enrique, Picazo, Nieves R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8895684/
https://www.ncbi.nlm.nih.gov/pubmed/35264819
http://dx.doi.org/10.1021/acs.organomet.1c00621

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8895684/
https://www.ncbi.nlm.nih.gov/pubmed/35264819
http://dx.doi.org/10.1021/acs.organomet.1c00621

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