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Sequential Insertion of Alkynes, Alkenes, and CO into the Pd–C Bond of ortho-Palladated Primary Phenethylamines: from η(3)-Allyl Complexes and Enlarged Palladacycles to Functionalized Arylalkylamines
[Image: see text] The eight-membered metallacycles arising from the insertion of 1 equiv of alkyne into the Pd–C bond of ortho-metalated homoveratrylamine and phentermine can further react with alkenes to give two different types of mononuclear complexes depending on the nature of the olefin. When t...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8895685/ https://www.ncbi.nlm.nih.gov/pubmed/35264820 http://dx.doi.org/10.1021/acs.organomet.0c00787 |