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Stabilization of intermediate spin states in mixed-valent diiron dichalcogenide complexes

The electronic structure and ground spin states, S, observed for mixed-valent iron–sulfur dimers (Fe(II)-Fe(III)) are typically determined by the Heisenberg exchange interaction, J, that couples the magnetic interaction of the two metal centres either ferromagnetically (J > 0, S = 9/2) or antifer...

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Detalles Bibliográficos
Autores principales: Henthorn, Justin T., Cutsail, George E., Weyhermüller, Thomas, DeBeer, Serena
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8898764/
https://www.ncbi.nlm.nih.gov/pubmed/35058610
http://dx.doi.org/10.1038/s41557-021-00853-5