Cargando…
Stabilization of intermediate spin states in mixed-valent diiron dichalcogenide complexes
The electronic structure and ground spin states, S, observed for mixed-valent iron–sulfur dimers (Fe(II)-Fe(III)) are typically determined by the Heisenberg exchange interaction, J, that couples the magnetic interaction of the two metal centres either ferromagnetically (J > 0, S = 9/2) or antifer...
Autores principales: | Henthorn, Justin T., Cutsail, George E., Weyhermüller, Thomas, DeBeer, Serena |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2022
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8898764/ https://www.ncbi.nlm.nih.gov/pubmed/35058610 http://dx.doi.org/10.1038/s41557-021-00853-5 |
Ejemplares similares
-
Determination of the iron(IV) local spin states of the Q intermediate of soluble methane monooxygenase by Kβ X-ray emission spectroscopy
por: Cutsail, George E., et al.
Publicado: (2022) -
XAS and EPR in Situ Observation of Ru(V) Oxo Intermediate in a Ru Water Oxidation Complex
por: Levin, Natalia, et al.
Publicado: (2021) -
From Ylides to Doubly Yldiide-Bridged Iron(II) High Spin Dimers via
Self-Protolysis
por: Yogendra, Sivathmeehan, et al.
Publicado: (2019) -
The Spectroscopy of Nitrogenases
por: Van Stappen, Casey, et al.
Publicado: (2020) -
Selenium Valence-to-Core
X-ray Emission Spectroscopy and Kβ HERFD X-ray
Absorption Spectroscopy as Complementary Probes of Chemical and Electronic
Structure
por: Henthorn, Justin T., et al.
Publicado: (2022)