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Heavy-Atom Tunneling in the Covalent/Dative Bond Complexation of Cyclo[18]carbon–Piperidine
[Image: see text] Recent quantum chemical computations demonstrated the electron-acceptance behavior of this highly reactive cyclo[18]carbon (C(18)) ring with piperidine (pip). The C(18)–pip complexation exhibited a double-well potential along the N–C reaction coordinate, forming a van der Waals (vd...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8900127/ https://www.ncbi.nlm.nih.gov/pubmed/35180344 http://dx.doi.org/10.1021/acs.jpcb.2c00218 |