Inverse Isotope Effects in Single-Crystal to Single-Crystal Reactivity and the Isolation of a Rhodium Cyclooctane σ-Alkane Complex

[Image: see text] The sequential solid/gas single-crystal to single-crystal reaction of [Rh(Cy(2)P(CH(2))(3)PCy(2))(COD)][BAr(F)(4)] (COD = cyclooctadiene) with H(2) or D(2) was followed in situ by solid-state (31)P{(1)H} NMR spectroscopy (SSNMR) and ex situ by solution quenching and GC-MS. This was...

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Detalles Bibliográficos
Autores principales: Doyle, Laurence R., Galpin, Martin R., Furfari, Samantha K., Tegner, Bengt E., Martínez-Martínez, Antonio J., Whitwood, Adrian C., Hicks, Scott A., Lloyd-Jones, Guy C., Macgregor, Stuart A., Weller, Andrew S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8900153/
https://www.ncbi.nlm.nih.gov/pubmed/35273423
http://dx.doi.org/10.1021/acs.organomet.1c00639

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8900153/
https://www.ncbi.nlm.nih.gov/pubmed/35273423
http://dx.doi.org/10.1021/acs.organomet.1c00639

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