Reactivity of Stabilized Vinyldiazo Compounds toward Alkenyl- and Alkynylsilanes under Gold Catalysis: Regio- and Stereoselective Synthesis of Skipped Dienes and Enynes

[Image: see text] We report the gold-catalyzed reaction of vinyldiazo compounds and alkenylsilanes to produce skipped dienes, which are common structural motifs in an array of bioactive compounds. This carbon–carbon bond-forming transformation proceeds with complete regio- and stereoselectivity with...

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Detalles Bibliográficos
Autores principales: Bernardo, Olaya, Yamamoto, Kota, Fernández, Israel, López, Luis A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8900156/
https://www.ncbi.nlm.nih.gov/pubmed/33983038
http://dx.doi.org/10.1021/acs.orglett.1c01381

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8900156/
https://www.ncbi.nlm.nih.gov/pubmed/33983038
http://dx.doi.org/10.1021/acs.orglett.1c01381

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