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Reactivity of Stabilized Vinyldiazo Compounds toward Alkenyl- and Alkynylsilanes under Gold Catalysis: Regio- and Stereoselective Synthesis of Skipped Dienes and Enynes

[Image: see text] We report the gold-catalyzed reaction of vinyldiazo compounds and alkenylsilanes to produce skipped dienes, which are common structural motifs in an array of bioactive compounds. This carbon–carbon bond-forming transformation proceeds with complete regio- and stereoselectivity with...

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Detalles Bibliográficos
Autores principales:	Bernardo, Olaya, Yamamoto, Kota, Fernández, Israel, López, Luis A.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2021
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8900156/ https://www.ncbi.nlm.nih.gov/pubmed/33983038 http://dx.doi.org/10.1021/acs.orglett.1c01381

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