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Electronic Structure and Donor Ability of an Unsaturated Triphosphorus-Bridged Dimolybdenum Complex

[Image: see text] The triphosphorus complex [Mo(2)Cp(2)(μ-η(3):η(3)-P(3))(μ-P(t)Bu(2))] was prepared in 83% yield by reacting the methyl complex [Mo(2)Cp(2)(μ-κ(1):η(2)-CH(3))(μ-P(t)Bu(2))(μ-CO)] with P(4) at 333 K, a process also giving small amounts of the methyldiphosphenyl complex [Mo(2)Cp(2)(μ-...

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Detalles Bibliográficos
Autores principales: Alvarez, M. Angeles, Casado-Ruano, Melodie, García, M. Esther, García-Vivó, Daniel, Guerra, Ana M., Ruiz, Miguel A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8901102/
https://www.ncbi.nlm.nih.gov/pubmed/34279915
http://dx.doi.org/10.1021/acs.inorgchem.1c01552