The key role of the latent N–H group in Milstein's catalyst for ester hydrogenation

We previously demonstrated that Milstein's seminal diethylamino-substituted PNN-pincer–ruthenium catalyst for ester hydrogenation is activated by dehydroalkylation of the pincer ligand, releasing ethane and eventually forming an NHEt-substituted derivative that we proposed is the active catalys...

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Detalles Bibliográficos
Autores principales: Pham, John, Jarczyk, Cole E., Reynolds, Eamon F., Kelly, Sophie. E., Kim, Thao, He, Tianyi, Keith, Jason M., Chianese, Anthony R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8901127/
https://www.ncbi.nlm.nih.gov/pubmed/35355805
http://dx.doi.org/10.1039/d1sc00703c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8901127/
https://www.ncbi.nlm.nih.gov/pubmed/35355805
http://dx.doi.org/10.1039/d1sc00703c

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