MicroED characterization of a robust cationic σ-alkane complex stabilized by the [B(3,5-(SF(5))(2)C(6)H(3))(4)](−) anion, via on-grid solid/gas single-crystal to single-crystal reactivity

Microcrystalline (∼1 μm) [Rh(Cy(2)PCH(2)CH(2)PCy(2))(norbornadiene)][S-BAr(F)(4)], [S-BAr(F)(4)] = [B(3,5-(SF(5))(2)C(6)H(3))(4)](−), reacts with H(2) in a single-crystal to single-crystal transformation to form the σ-alkane complex [Rh(Cy(2)PCH(2)CH(2)PCy(2))(norbornane)][S-BAr(F)(4)], for which th...

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Detalles Bibliográficos
Autores principales: Doyle, Laurence R., Thompson, Emily A., Burnage, Arron L., Whitwood, Adrian C., Jenkins, Huw T., Macgregor, Stuart A., Weller, Andrew S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8902584/
https://www.ncbi.nlm.nih.gov/pubmed/35156982
http://dx.doi.org/10.1039/d2dt00335j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8902584/
https://www.ncbi.nlm.nih.gov/pubmed/35156982
http://dx.doi.org/10.1039/d2dt00335j

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