Cargando…

MicroED characterization of a robust cationic σ-alkane complex stabilized by the [B(3,5-(SF(5))(2)C(6)H(3))(4)](−) anion, via on-grid solid/gas single-crystal to single-crystal reactivity

Microcrystalline (∼1 μm) [Rh(Cy(2)PCH(2)CH(2)PCy(2))(norbornadiene)][S-BAr(F)(4)], [S-BAr(F)(4)] = [B(3,5-(SF(5))(2)C(6)H(3))(4)](−), reacts with H(2) in a single-crystal to single-crystal transformation to form the σ-alkane complex [Rh(Cy(2)PCH(2)CH(2)PCy(2))(norbornane)][S-BAr(F)(4)], for which th...

Descripción completa

Detalles Bibliográficos
Autores principales:	Doyle, Laurence R., Thompson, Emily A., Burnage, Arron L., Whitwood, Adrian C., Jenkins, Huw T., Macgregor, Stuart A., Weller, Andrew S.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8902584/ https://www.ncbi.nlm.nih.gov/pubmed/35156982 http://dx.doi.org/10.1039/d2dt00335j

Ejemplares similares

Inverse Isotope Effects in Single-Crystal to Single-Crystal Reactivity and the Isolation of a Rhodium Cyclooctane σ-Alkane Complex
por: Doyle, Laurence R., et al.
Publicado: (2022)

Room Temperature Acceptorless Alkane Dehydrogenation from Molecular σ-Alkane Complexes
por: McKay, Alasdair I., et al.
Publicado: (2019)

Selectivity of Rh⋅⋅⋅H−C Binding in a σ‐Alkane Complex Controlled by the Secondary Microenvironment in the Solid State
por: Furfari, Samantha K., et al.
Publicado: (2021)

A Series of Crystallographically Characterized Linear and Branched σ-Alkane Complexes of Rhodium: From Propane to 3-Methylpentane
por: Bukvic, Alexander J., et al.
Publicado: (2021)

Single-Crystal to Single-Crystal Addition of H(2) to [Ir((i)Pr-PONOP)(propene)][BAr(F)(4)] and Comparison Between Solid-State and Solution Reactivity
por: Royle, Cameron G., et al.
Publicado: (2022)

A Structurally Characterized Cobalt(I) σ‐Alkane Complex
por: Boyd, Timothy M., et al.
Publicado: (2020)

Strain Measurement in Single Crystals by 4D-ED
por: Lábár, János L., et al.
Publicado: (2023)

Application of GRID to Foreign Atom Localization in Single Crystals
por: Karmann, A., et al.
Publicado: (2000)

Solid-state molecular organometallic chemistry. Single-crystal to single-crystal reactivity and catalysis with light hydrocarbon substrates
por: Chadwick, F. Mark, et al.
Publicado: (2017)

Crystal structures of eight mono-methyl alkanes (C(26)–C(32)) via single-crystal and powder diffraction and DFT-D optimization
por: Brooks, Lee, et al.
Publicado: (2015)

Comparison of (K(0.5)Na(0.5))NbO(3) Single Crystals Grown by Seed-Free and Seeded Solid-State Single Crystal Growth
por: Fisher, John G., et al.
Publicado: (2023)

Study of Interatomic Potentials Using the Crystal-GRID Method on Oriented Single Crystals of Ni, Fe, and Cr
por: Stritt, N., et al.
Publicado: (2000)

Spectroscopy of single Pr(3+) ion in LaF(3) crystal at 1.5 K
por: Nakamura, Ippei, et al.
Publicado: (2014)

Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and [AuCl(4)](−)
por: López-Cabrelles, Javier, et al.
Publicado: (2016)

Growth, Structure and Optical Characterization of Rb(3)Ti(3)P(5)O(20) Single Crystal
por: Zhao, Jianfu, et al.
Publicado: (2022)

Optimizing K(0.5)Na(0.5)NbO(3) Single Crystal by Engineering Piezoelectric Anisotropy
por: Li, Weixiong, et al.
Publicado: (2021)

A cationic thorium–organic framework with triple single-crystal-to-single-crystal transformation peculiarities for ultrasensitive anion recognition
por: Li, Zi-Jian, et al.
Publicado: (2021)

Crystallization of CsPbBr(3) single crystals in water for X-ray detection
por: Peng, Jiali, et al.
Publicado: (2021)

Thin MAPb(0.5)Sn(0.5)I(3) Perovskite Single Crystals for Sensitive Infrared Light Detection
por: Wu, Jinming, et al.
Publicado: (2022)

Detection of σ-alkane complexes of manganese by NMR and IR spectroscopy in solution: (η(5)-C(5)H(5))Mn(CO)(2)(ethane) and (η(5)-C(5)H(5))Mn(CO)(2)(isopentane)
por: Torres, Olga, et al.
Publicado: (2015)

Crystal structures of the components of the Staphylococcus aureus leukotoxin ED
por: Nocadello, S., et al.
Publicado: (2016)

Reversible First-Order Single Crystal to Single Crystal Thermal Phase Transition in [(CH(3))(3)CNH(3)](4)[V(4)O(12)]
por: Vitoria, Pablo, et al.
Publicado: (2022)

Synthesis of single-crystal low-loss LiB(3)O(5) nanowire and its optical properties
por: Qu, Guang-Yuan, et al.
Publicado: (2016)

Ortho-aryl substituted DPEphos ligands: rhodium complexes featuring C–H anagostic interactions and B–H agostic bonds
por: Race, James J., et al.
Publicado: (2021)

Liquid and single crystals
por: Goosen, Jai
Publicado: (2019)

Crystal Structure of Reovirus Attachment Protein σ1 in Complex with Sialylated Oligosaccharides
por: Reiter, Dirk M., et al.
Publicado: (2011)

Structural and Theoretical Study of Copper(II)-5-fluoro Uracil Acetate Coordination Compounds: Single-Crystal to Single-Crystal Transformation as Possible Humidity Sensor
por: Vegas, Verónica G., et al.
Publicado: (2023)

Reversible Thermochromism of Nickel(II) Complexes and Single-Crystal-to-Single-Crystal Transformation
por: Pitchaimani, Jayaraman, et al.
Publicado: (2019)

Shape Preserving Single Crystal to Amorphous to Single Crystal Polymorphic Transformation Is Possible
por: Renier, Olivier, et al.
Publicado: (2021)

Protein crystallization analysis on the World Community Grid
por: Cumbaa, Christian A., et al.
Publicado: (2010)

Ce(3+), Pr(3+) Co-Doped Lu(3)Al(5)O(12) Single Crystals and Ceramics: A Comparative Study
por: Xiong, Yifei, et al.
Publicado: (2022)

Additive manufacturing of micrometric crystallization vessels and single crystals
por: Halevi, Oded, et al.
Publicado: (2016)

Multiple twinning in cubic crystals: geometric/algebraic study and its application for the identification of the Σ3(n) grain boundaries
por: Cayron, Cyril
Publicado: (2007)

Crystal structure of [UO(2)(NH(3))(5)]NO(3)·NH(3)
por: Woidy, Patrick, et al.
Publicado: (2016)

Effects of ITO Substrate Hydrophobicity on Crystallization and Properties of MAPbBr(3) Single-Crystal Thin Films
por: Di, Haipeng, et al.
Publicado: (2020)

Crystal structure of 3,3′-biisoxazole-5,5′-bis(methylene) dinitrate (BIDN)
por: Sausa, Rosario C., et al.
Publicado: (2017)

Micropillar compression deformation of single crystals of α-Nb(5)Si(3) with the tetragonal D8(l) structure
por: Kishida, Kyosuke, et al.
Publicado: (2021)

The 3.4 GHz BAW RF Filter Based on Single Crystal AlN Resonator for 5G Application
por: Ding, Rui, et al.
Publicado: (2022)

Single-crystal two-dimensional material epitaxy on tailored non-single-crystal substrates
por: Li, Xin, et al.
Publicado: (2022)

Anion exchange coupled with the reduction and dimerisation of a copper(ii) nitrate complex of tripyridyl dithioether via a single-crystal-to-single-crystal transformation
por: Lee, Hyeong-Hwan, et al.
Publicado: (2017)

Cannot write session to /tmp/vufind_sessions/sess_n21gh03nldrch6sgonfe7qh5f6