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Stereoselective, Ruthenium-Photocatalyzed Synthesis of 1,2-Diaminotruxinic Bis-amino Acids from 4-Arylidene-5(4H)-oxazolones

[Image: see text] The irradiation of (Z)-2-phenyl-4-aryliden-5(4H)-oxazolones 1 in deoxygenated CH(2)Cl(2) at 25 °C with blue light (465 nm) in the presence of [Ru(bpy)(3)](BF(4))(2) (5% mole ratio) as a triplet photocatalyst promotes the [2+2] photocycloaddition of the C=C bonds of the 4-arylidene...

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Detalles Bibliográficos
Autores principales: Sierra, Sonia, Gomez, M. Victoria, Jiménez, Ana I., Pop, Alexandra, Silvestru, Cristian, Marín, Maria Luisa, Boscá, Francisco, Sastre, Germán, Gómez-Bengoa, Enrique, Urriolabeitia, Esteban P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8902759/
https://www.ncbi.nlm.nih.gov/pubmed/35143202
http://dx.doi.org/10.1021/acs.joc.1c03092