Cargando…
A (μ-hydrido)diborane(4) anion and its coordination chemistry with coinage metals
A tetra(o-tolyl) (μ-hydrido)diborane(4) anion 1, an analogue of [B(2)H(5)](−) species, was facilely prepared through the reaction of tetra(o-tolyl)diborane(4) with sodium hydride. Unlike common sp(2)–sp(3) diborane species, 1 exhibited a σ-B–B bond nucleophilicity towards NHC-coordinated transition-...
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8905795/ https://www.ncbi.nlm.nih.gov/pubmed/35382458 http://dx.doi.org/10.1039/d2sc00318j |