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A (μ-hydrido)diborane(4) anion and its coordination chemistry with coinage metals

A tetra(o-tolyl) (μ-hydrido)diborane(4) anion 1, an analogue of [B(2)H(5)](−) species, was facilely prepared through the reaction of tetra(o-tolyl)diborane(4) with sodium hydride. Unlike common sp(2)–sp(3) diborane species, 1 exhibited a σ-B–B bond nucleophilicity towards NHC-coordinated transition-...

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Detalles Bibliográficos
Autores principales:	Mao, Xiaofeng, Zhang, Jie, Lu, Zhenpin, Xie, Zuowei
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8905795/ https://www.ncbi.nlm.nih.gov/pubmed/35382458 http://dx.doi.org/10.1039/d2sc00318j

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