Hypervalent iodine-mediated β-difluoroalkylboron synthesis via an unusual 1,2-hydrogen shift enabled by boron substitution

β-Difluoroalkylborons, featuring functionally important CF(2) moiety and synthetically valuable boron group, have great synthetic potential while remaining synthetically challenging. Herein we report a hypervalent iodine-mediated oxidative gem-difluorination strategy to realize the construction of g...

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Detalles Bibliográficos
Autores principales: Lv, Wen-Xin, Li, Yin, Cai, Yuan-Hong, Tan, Dong-Hang, Li, Zhan, Li, Ji-Lin, Li, Qingjiang, Wang, Honggen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8905827/
https://www.ncbi.nlm.nih.gov/pubmed/35382474
http://dx.doi.org/10.1039/d1sc06508d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8905827/
https://www.ncbi.nlm.nih.gov/pubmed/35382474
http://dx.doi.org/10.1039/d1sc06508d

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