Diboramacrocycles: reversible borole dimerisation–dissociation systems

We report that the outcome of the tin–boron exchange reaction of a mixed thiophene-benzo-fused stannole with aryldibromoboranes is associated with the steric bulk of the aryl substituent of the borane reagent, leading to either boroles or large diboracycles as products. NMR spectroscopic studies ind...

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Detalles Bibliográficos
Autores principales: Fuchs, Sonja, Jayaraman, Arumugam, Krummenacher, Ivo, Haley, Laura, Baštovanović, Marta, Fest, Maximilian, Radacki, Krzysztof, Helten, Holger, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8905844/
https://www.ncbi.nlm.nih.gov/pubmed/35382462
http://dx.doi.org/10.1039/d1sc06908j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8905844/
https://www.ncbi.nlm.nih.gov/pubmed/35382462
http://dx.doi.org/10.1039/d1sc06908j

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